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Beilstein J. Org. Chem. 2020, 16, 351–361, doi:10.3762/bjoc.16.34
Graphical Abstract
Scheme 1: [HSO3-BDBU]H2PO4-promoted oligomerization and separation.
Scheme 2: Structures of ILs used in this work.
Figure 1: Monitoring oligomerization process by 1H NMR (400 MHz, CDCl3).
Figure 2: Reusability of the IL catalyst. Reaction conditions: 10 g (30 mmol) ricinoleic acid, 190 °C, 6 h, 5...
Figure 3: 1H NMR (400 MHz, DMSO-d6) spectra of [HSO3-BDBU]H2PO4: a) Fresh one; b) used one after five cycles.
Scheme 3: Proposed mechanism for [HSO3-BDBU]H2PO4 catalyzed oligomeric ricinoleic acid synthesis.
Beilstein J. Org. Chem. 2014, 10, 1959–1966, doi:10.3762/bjoc.10.204
Scheme 1: Reactions of CO2 with amino-group containing absorbents (a), base/proton donor binary system (b) or...
Figure 1: Typical optimized structures of complex cations derived from chelation between Li+ and neutral liga...
Figure 2: (a) Comparison of the thermal stability between the neutral ligands and the corresponding chelated ...
Figure 3: In situ FTIR spectra of neutral ligands and the corresponding chelated ionic liquids after reaction...
Figure 4: Influence of the ratio of LiNTf2/neutral ligands (PEG150MeTMG and PEG150MeBu2N) on the CO2 capacity...
Figure 5: The quantum chemistry calculations (enthalpy changes) of the reaction between CO2 and [PEG150MeTMGL...